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uses of halogenated alkanes and alkenes, Exams of Organic Chemistry

uses are given for few selected halogenated alkanes and alkenes

Typology: Exams

2017/2018

Uploaded on 04/11/2018

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USESOF ETHYL CHLORIDE (C2H5Cl):
1. Ethyl chloride is a suitable chlorinated solvent in view of its physical and
chemical properties. It is relatively inert, more stable and less toxic than
other chlorinated solvents.
2. It is used as a skin refrigerant. When applied as a fine spray, superficial
tissues become freezed and peripheral nerve endings get insensitive. Finally
spray acts as a local anesthetic agent. (Duration: 1 min)
3. It is used as local anaesthetic before skin biopsy, sport injuries and ear
piercing.
4. It is used as an intermediate in the production of various coatings, films,
plastics and gasoline additives.
5. It is used as aerosol spray propellent, blowing agent in foam packaging and
in production of dyes, pharmaceuticals and other commercial chemicals.
6. It is used in the preparation of ethyl cellulose. Ethyl cellulose is produced
when ethyl chloride reacts with sodium cellulose. Ethyl cellulose resins are
widely used for coating, film forming, binding and enhancing the
performance of different products.
7. Ethyl chloride is used in preparation of styrene. It is obtained when benzene
reacts with ethyl chloride. Styrene is extensively used in the manufacturing
of rubber, plastic, insulation, fiber glass, automobile, boat parts and food
containers.
8. It is also used in the preparation of tetra ethyl lead, when lead-sodium alloy
reacts with ethyl chloride, tetra ethyl lead is produced
9. It is also used as a reactive intermediate in several chemical reactions
Eg. Aluminium polymer catalysts, adhesives
10. It is used as ethylating agent in the manufacturing of dyes and drugs
11. Used as pulp vitality tester in density
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USESOF ETHYL CHLORIDE (C 2 H 5 Cl):

  1. Ethyl chloride is a suitable chlorinated solvent in view of its physical and chemical properties. It is relatively inert, more stable and less toxic than other chlorinated solvents.
  2. It is used as a skin refrigerant. When applied as a fine spray, superficial tissues become freezed and peripheral nerve endings get insensitive. Finally spray acts as a local anesthetic agent. (Duration: 1 min)
  3. It is used as local anaesthetic before skin biopsy, sport injuries and ear piercing.
  4. (^) It is used as an intermediate in the production of various coatings, films, plastics and gasoline additives.
  5. It is used as aerosol spray propellent, blowing agent in foam packaging and in production of dyes, pharmaceuticals and other commercial chemicals.
  6. It is used in the preparation of ethyl cellulose. Ethyl cellulose is produced when ethyl chloride reacts with sodium cellulose. Ethyl cellulose resins are widely used for coating, film forming, binding and enhancing the performance of different products.
  7. Ethyl chloride is used in preparation of styrene. It is obtained when benzene reacts with ethyl chloride. Styrene is extensively used in the manufacturing of rubber, plastic, insulation, fiber glass, automobile, boat parts and food containers.
  8. It is also used in the preparation of tetra ethyl lead, when lead-sodium alloy reacts with ethyl chloride, tetra ethyl lead is produced
  9. It is also used as a reactive intermediate in several chemical reactions Eg. Aluminium polymer catalysts, adhesives
  10. It is used as ethylating agent in the manufacturing of dyes and drugs
  11. Used as pulp vitality tester in density
  1. Used in the treatment of pain evoked by insect bites and burns
  2. Used as an adjunct in the treatment of tinea lesions and creeping eruptions
  3. Also used as a counter irritant for the relief of myofacial and visceral pain syndromes
  4. (^) It is largely used as a blowing agent in foamed plastics

CHLOROFORM (CHCl 3 ):

  1. Mainly used to produce the Freon refrigerant R-
  2. Smaller amounts are used as solvent in pharmaceutical industry.
  3. Used in preparing dyes, pesticides
  4. As a solvent in academic research labs
  5. Used in the extraction of alkaloids from plant material. It is commercially used to extract morphine from poppies and scopolamine from datura plants
  6. It is used to separate DNA from cellular material, along with phenol. In presence of buffer, phenol and chloroform DNA can be obtained as supernatant
  7. Deuteriated chloroform (CDCl 3 ) is used as solvent in NMR spectroscopy
  8. Chloroform is also used as an extraction solvent for fats, oils, greases, rubber, waxes, gutta percha, resins, lacquers, floor polishes, artificial silk, gums and adhesives
  9. It is used in the purification of antibiotics, alkaloids, vitamins and flavours
  10. It is used as dry cleaning agent
  11. Used as fumigant
  12. Used as fire extringuishers to lower the freezing temperature of CCl (^4)
  13. Previously it was used as a local anaesthetic agent. Now its use has been declined due to the availability of better agents
  14. It is also used to control screw worm in animals.
  1. It is used as typewriter correction fluid, paint remover, paint stripper, adhesive, spot remover, rug-cleaning fluid

TETRACHLOROETHYLENE ( Cl^2 C=CCl^2 )

  1. It is volatile, highly stable and non-flammable
  2. Widely used in dry cleaning
  3. Used to degrease metal parts in the automotive industries
  4. Used as spot removers
  5. Pain stripper
  6. It is also used in neutrino detectors where neutrino interacts with a neutron in the chlorine atom and converts it to a proton to form argon
  7. Used as a solvent in dry-cleaning
  8. Used as a precursor in the production of chlorofluoro carbons
  9. Used in the production of pain remover, printing ink, formulation of adhesives, cleaning fluids
  10. Extensively used in textile industry as a component of aerosol dry- cleaning product
  11. Used as a scouring solvent that removes oils from fabrics after knitting and weaving operations
  12. Used as carrier solvent for sizing, desizing and in water repellents
  13. Extensively used as dry-cleaning agent
  14. To clean contaminated metal parts and other fabricated materials
  15. (^) To remove soot from industrial boilers
  16. It was used as anthelmintic in the treatment of hook worm and nematode infections

DICHLOROMETHANE (CH 2 Cl 2 ):

  1. Used as a solvent for many chemical processes and reactions
  2. Pain stripper, degreaser
  3. Used to decaffeinate coffee and tea
  4. Used to prepare extracts of hops and other flavoring agents (Hops is used

for anxiety, inability to sleep and other sleep disorders, restlessness, tension, excitability, attention deficit-hyperactivity disorder (ADHD), nervousness, and irritability). Hop extract is used to prepare creams and lotions

  1. Used as an aerosol spray propellent
  2. Used as a blowing agent for polyurethane foams (A blowing agent is an

agent which is capable of producing a cellular structure via a foaming process in substances that undergo hardening or phase transition; polymers, plastics and metals)

  1. Used to remove paints
  2. Used as a solvent and cleaning agent in the textiles, electronics, metals, plastics, pesticide industries
  3. Used as blowing/cleaning agent in the urethane foam industry
  4. Used as fumigant for strawberries and grains
  5. Used as an aneasthetic (An anestheticis a drug to prevent pain)
  6. Used in the extraction process of caffeine, cocoa, fats, spices, beer hops
  7. Used as heat transfer agent in refrigeration product
  8. Used as a solvent in paint and varnish strippers
  9. Used in bathtub refinishing
  10. Used as an extraction solvent in the food and beverage manufacturing

industry

  1. Decaffeination of coffee and tea
  2. Used in the processing of spices
  1. Used in chlorofluoro carbon propellents and refrigerants
  2. Making nylons, soaps, insecticides
  3. Used as a solvent for IR(Infra Red) spectroscopy
  4. Used as a solvent for NMR (Nuclear magnetic resonance spectroscopy) spectroscopy
  5. It is a solvent in halogenation reactions
  6. Used in Wohl-Ziegler bromination
  7. Used as a solvent for oils, fats, lacquers, varnishes, rubber waxes, resins
  8. Grain fumigant (In mixture with carbon tetrachloride, carbon disulphide (CS2) is very usefulas grain fumigant (16.5 percent CS2 82.5 percent carbon tetrachloride and 1.0 percent inert ingredients).

IODOFORM (CHI 3 ):

  1. Used as disinfectant
  2. Once used as a medicine as healing and antiseptic dressing for wounds and sores
  3. Used in ear powders for dogs and cats along with ZnO and propanoic acid to prevent ear infection and facilitate removal of hair
  4. Anti-infective agent
  5. Veterinary use: Antiseptic, disinfectant for superficial lesions and in the female reproductive tract
  6. Iodoform may cause poisoning (vomiting, rapid pulse, hallucinations, fever). It may led to coma or death
  7. Skin absorption may lead to vision impairment, total blindness
  8. Iodoform is commonly used in dental practice as an antiseptic either alone, or in combination with eucalyptus oil or glycerine for the treatment of dry socket, as a dressing for the large cystic defects and for

the soft tissue dressing in the cases of dehiscence of wounds or to promote healing by secondary intention