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Solved query for limiting reagents, Exercises of Chemistry

The process of bromination of acetanilide and how to determine the limiting reagents and calculate the percent yield. It includes a balanced chemical equation for the reaction and the theoretical yield of bromoacetanilide.

Typology: Exercises

2019/2020

Available from 04/01/2023

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For the bromination of acetanilide: 0.5 g of acetanilide, 2 mL of glacial acetic acid, 3.7 mL of 1.0 M
bromine in acetic acid was used to create bromoacetanilide Determine the limiting reagents (show all
work) and calculate the percent yield ?
Ans) To determine the limiting reagent, we need to compare the number of moles of acetanilide and
bromine in acetic acid.
First, let's calculate the number of moles of bromine in acetic acid:
We can see that the number of moles of bromine in acetic acid and acetanilide is the same, meaning
that neither reagent is in excess, and they are both limiting reagents.
To calculate the theoretical yield, we need to calculate the number of moles of bromoacetanilide that
can be formed. Since both reactants are limiting, the reaction will go to completion, and all of the
bromine in acetic acid and acetanilide will be used.
The balanced chemical equation for the reaction is:
Acetanilide + Br2 -> bromoacetanilide + HBr + HOAc
From the balanced equation, we can see that 1 mole of acetanilide reacts with 1 mole of Br2 to produce
1 mole of Bromo acetanilide.
So the theoretical yield of Bromo acetanilide is:
N(Bromo acetanilide) = n(acetanilide) = 0.0037 mol
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For the bromination of acetanilide: 0.5 g of acetanilide, 2 mL of glacial acetic acid, 3.7 mL of 1.0 M bromine in acetic acid was used to create bromoacetanilide Determine the limiting reagents (show all work) and calculate the percent yield? Ans) To determine the limiting reagent, we need to compare the number of moles of acetanilide and bromine in acetic acid. First, let's calculate the number of moles of bromine in acetic acid: We can see that the number of moles of bromine in acetic acid and acetanilide is the same, meaning that neither reagent is in excess, and they are both limiting reagents. To calculate the theoretical yield, we need to calculate the number of moles of bromoacetanilide that can be formed. Since both reactants are limiting, the reaction will go to completion, and all of the bromine in acetic acid and acetanilide will be used.

The balanced chemical equation for the reaction is:

Acetanilide + Br2 -> bromoacetanilide + HBr + HOAc

From the balanced equation, we can see that 1 mole of acetanilide reacts with 1 mole of Br2 to produce 1 mole of Bromo acetanilide. So the theoretical yield of Bromo acetanilide is: N(Bromo acetanilide) = n(acetanilide) = 0.0037 mol

To calculate the percent yield, we need to know the actual yield. Let’s assume that the product was isolated and purified, and the mass of the product obtained was 0.4 g. The percent yield is: Percent yield = (actual yield / theoretical yield) x 100% Percent yield = (0.4 g / (0.0037 mol x 241.2 g/mol)) x 100% Percent yield = 44.4%

The limiting reagents are both acetanilide and bromine in acetic acid, and the

percent yield of Bromo acetanilide is 44.4%