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Simple Models - Atmospheric Chemistry - Lecture Slides, Slides of Chemistry

Major topics of Atmospheric Chemistry course are Acid Rain, Aerosol, Aerosols Optics, Geochemical Cycles, Global Models, Trop Ozone Pollution and many others. These lecture slides contain following keywords: Simple Models, Atmospheric Evolution of a Species, Continuity Equation, Clausius-Clapeyron Equation, One-Box Model, Global Box Model for Co2, Latitudinal Gradient, Evolution of a Pollution Plume, Puff Model, Lagrangian Receptor-Oriented Modeling

Typology: Slides

2012/2013

Uploaded on 08/21/2013

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SIMPLE MODELS
Define
problem of
interest
Design model; make
assumptions needed
to simplify equations
and make them solvable
Evaluate
model with
observations
Apply model:
make hypotheses,
predictions
Improve model, characterize its error
The atmospheric evolution of a species X is given by the continuity equation
This equation cannot be solved exactly need to construct model
(simplified representation of complex system)
Design
observational
system to test
model
[] ([ ])
XXXX
X
E
XPLD
t

U
local change in
concentration
with time
transport
(flux divergence;
U is wind vector)
chemical production and loss
(depends on concentrations
of other species)
emission deposition
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SIMPLE MODELS

Defineproblem ofinterest

Design model; makeassumptions neededto simplify equationsand make them solvable

Evaluatemodel withobservations

Apply model:make hypotheses,predictions Improve model, characterize its error

The atmospheric evolution of a species X is given by the

continuity equation

This equation cannot be solved exactly

need to construct

model

(simplified representation of complex system)

Designobservationalsystem to testmodel

[

]

(

[

])

X

X

X

X

X

E

X

P

L

D

t

  

U

local change inconcentration

with time

transport(flux divergence;U is wind vector)

chemical production and loss(depends on concentrationsof other species)

emission

deposition

CLAUSIUS-CLAPEYRON EQUATION:

P

H2O, SAT

f(T)

2

,

1

1

exp[

(

)]

H

O SAT

o

P

A

B

T

T

A

= 6.11 hPa B

= - 5310 K
T

o

= 273 K

(hPa)^ H2O,SAT P

T
(K)

EXAMPLE: GLOBAL BOX MODEL FOR CO

2

(Pg C yr

IPCC [2001]
IPCC [2001]

SPECIAL CASE:

SPECIES WITH CONSTANT SOURCE, 1

st

ORDER SINK

( )

(0)

(

)

kt

kt

dm

S

S

km

m t

m

e

e

dt

k

Steady statesolution(

dm/dt = 0)

Initial condition

m(0)

Characteristic time

k

for

reaching steady state

decay of initial condition

If

S, k

are constant over

t >>

,^

then

dm/dt

0 and

m

S/k:

quasi steady state

Illustrates long time scale for interhemispheric exchange; can use 2-box modelto place constraints on CO

2

sources/sinks in each hemisphere

LATITUDINAL GRADIENT OF CO

2

EULERIAN

RESEARCH MODELS SOLVE MASS BALANCE

EQUATION IN 3-D ASSEMBLAGE OF GRIDBOXES

Solve continuity equationfor individual gridboxes

Models can presently afford~ 10

6

gridboxes

In global models, this implies a horizontal resolution of 100-500 kmin horizontal and ~ 1 km in vertical •

Drawbacks: “numerical diffusion”, computational expense

The mass balance equation is then the finite-difference approximationof the continuity equation.

PUFF MODEL: FOLLOW AIR PARCEL MOVING WITH WIND C

X

x

o

,^

t

o

C

X

x,

t

wind

In the moving puff,

X

dC

E

P

L

D

dt

…no transport terms! (they’re implicit in the trajectory)

Application to the chemical evolution of an isolated pollution plume:

C

X

C

X,b

,

(

)

X

dilution

X

X b

dC

E

P

L

D

k

C

C

dt

In pollution plume,

COLUMN MODEL FOR TRANSPORT ACROSS

URBAN AIRSHED

Temperature inversion(defines “mixing depth”)

Emission

E

In column moving across city,

X

X

dC

E

k

C

dx

Uh

U

C

X

L

x docsity.com

LAGRANGIAN RECEPTOR-ORIENTED MODELING

Run Lagrangian model backward from receptor location,with points released at receptor location only

Efficient cost-effective quantification of source influence distribution on receptor (“footprint”)

backward in time