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Lifeguard Limescale Remover
Revision: 2017-09-09 Version: 07.
According to Regulation (EC) No 1907/
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name: Lifeguard Limescale Remover
Lifeguard ® Used under authority from S.C. Johnson & Son Inc., Racine, Wisconsin, U.S.A.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses:
For professional use only.
AISE-P307 - Descaling agent. Manual process
Uses advised against: Uses other than those identified are not recommended
1.3 Details of the supplier of the safety data sheet
Contact details
Diversey Ltd
Weston Favell Centre, Northampton NN3 8PD, United Kingdom
Tel: 01604 405311, Fax: 01604 406809
Regulatory Email: customerservice.uk@diversey.com
1.4 Emergency telephone number
For medical or environmental emergency only:
call 0800 052 0185
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Eye Dam. 1 (H318)
Met. Corr. 1 (H290)
2.2 Label elements
Signal word: Danger.
Contains alkyl alcohol ethoxylate (Trideceth-8).
Hazard statements:
H318 - Causes serious eye damage.
H290 - May be corrosive to metals.
Precautionary statements:
P280 - Wear eye or face protection.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P310 - Immediately call a POISON CENTRE, doctor or physician.
2.3 Other hazards
No other hazards known
The product does not meet the criteria for PBT or vPvB in accordance with Regulation (EC) No 1907/2006, Annex XIII
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Ingredient(s) EC number CAS number REACH number Classification Notes Weight percent phosphoric acid 231-633-2 7664-38-2 01-2119485924-24 Skin Corr. 1B (H314) 3-
Lifeguard Limescale Remover
Met. Corr. 1 (H290) alkyl alcohol ethoxylate Polymer* 69011-36-5 [4] Acute Tox. 4 (H302) Eye Dam. 1 (H318)
- Polymer. For the full text of the H and EUH phrases mentioned in this Section, see Section 16. Workplace exposure limit(s), if available, are listed in subsection 8.1. [1] Exempted: ionic mixture. See Regulation (EC) No 1907/2006, Annex V, paragraph 3 and 4. This salt is potentially present, based on calculation, and included for classification and labelling purposes only. Each starting material of the ionic mixture is registered, as required. [2] Exempted: included in Annex IV of Regulation (EC) No 1907/2006. [3] Exempted: Annex V of Regulation (EC) No 1907/2006. [4] Exempted: polymer. See Article 2(9) of Regulation (EC) No 1907/2006. SECTION 4: First aid measures
4.1 Description of first aid measures
Inhalation: Get medical attention or advice if you feel unwell.
Skin contact: Wash skin with plenty of lukewarm, gently flowing water. If skin irritation occurs: Get medical advice
or attention.
Eye contact: Immediately rinse eyes cautiously with lukewarm water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Immediately call a POISON CENTRE, doctor or
physician.
Ingestion: Immediately drink 1 glass of water. Get medical attention or advice if you feel unwell.
Self-protection of first aider: Consider personal protective equipment as indicated in subsection 8.2.
4.2 Most important symptoms and effects, both acute and delayed
Inhalation: No known effects or symptoms in normal use.
Skin contact: No known effects or symptoms in normal use.
Eye contact: Causes severe or permanent damage.
Ingestion: No known effects or symptoms in normal use.
4.3 Indication of any immediate medical attention and special treatment needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found
in section 11.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol-resistant foam.
5.2 Special hazards arising from the substance or mixture
No special hazards known.
5.3 Advice for firefighters
As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Wear eye/face protection.
6.2 Environmental precautions
Do not allow to enter drainage system, surface or ground water. Dilute with plenty of water.
6.3 Methods and material for containment and cleaning up
Absorb with liquid-binding material (sand, diatomite, universal binders, sawdust).
6.4 Reference to other sections
For personal protective equipment see subsection 8.2. For disposal considerations see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Measures to prevent fire and explosions:
No special precautions required.
Measures required to protect the environment:
For environmental exposure controls see subsection 8.2.
Advices on general occupational hygiene:
Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not mix with
other products unless adviced by Diversey. Wash hands before breaks and at the end of workday. Wash face, hands and any exposed skin
thoroughly after handling. Take off immediately all contaminated clothing. Use personal protective equipment as required. Avoid contact with
eyes. Use only with adequate ventilation.
Lifeguard Limescale Remover
Recommended safety measures for handling the undiluted product:
Covering activities such as filling and transfer of product to application equipment, flasks or buckets
Appropriate engineering controls: If the product is diluted by using specific dosing systems with no risk of splashes or direct skin
contact, the personal protection equipment as described in this section is not required.
Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel.
Personal protective equipment
Eye / face protection: Safety glasses or goggles (EN 166).
Hand protection: Rinse and dry hands after use. For prolonged contact protection for the skin may be necessary.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.
Environmental exposure controls: Should not reach sewage water or drainage ditch undiluted or unneutralised.
Recommended safety measures for handling the diluted product:
Recommended maximum concentration (%): 10
Appropriate engineering controls: No special requirements under normal use conditions.
Appropriate organisational controls: No special requirements under normal use conditions.
Personal protective equipment
Eye / face protection: Safety glasses are not normally required. However, their use is recommended in those cases
where splashes may occur when handling the product.
Hand protection: Rinse and dry hands after use. For prolonged contact protection for the skin may be necessary.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.
Environmental exposure controls: No special requirements under normal use conditions.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Information in this section refers to the product, unless it is specifically stated that substance data is listed
Physical State: Liquid
Colour: Clear, Purple
Odour: Slightly perfumed
Odour threshold: Not applicable
Substance data, boiling point Ingredient(s) Value (°C) Method Atmospheric pressure (hPa) phosphoric acid 158 Method not given 1013 alkyl alcohol ethoxylate > 200 Method not given ( UN Manual of Tests and Criteria, section 32, L.2 ) Substance data, flammability or explosive limits, if available: Substance data, vapour pressure Ingredient(s) Value (Pa) Method Temperature (°C) phosphoric acid 4 Method not given 20 alkyl alcohol ethoxylate Negligible Method not given 20-
Method / remark
pH: < 2 (neat)
Melting point/freezing point (°C): Not determined Not relevant to classification of this product
Initial boiling point and boiling range (°C): Not determined
Method / remark
Flash point (°C): Not applicable.
Sustained combustion: Not applicable.
Evaporation rate: Not determined
Flammability (solid, gas): Not determined
Upper/lower flammability limit (%): Not determined
Method / remark
Vapour pressure: Not determined
Method / remark
Vapour density: Not determined
Relative density: ≈1. 0 6 ( 2 0°C)
Lifeguard Limescale Remover
Solubility in / Miscibility with Water: Fully miscible
Substance data, solubility in water Ingredient(s) Value (g/l) Method Temperature (°C) phosphoric acid Soluble alkyl alcohol ethoxylate Soluble Method not given 20 Substance data, partition coefficient n-octanol/water (log Kow): see subsection 12.
Decomposition temperature: Not applicable.
9.2 Other information
Substance data, dissociation constant, if available: SECTION 10: Stability and reactivity
10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.
10.2 Chemical stability
Stable under normal storage and use conditions.
10.3 Possibility of hazardous reactions
No hazardous reactions known under normal storage and use conditions.
10.4 Conditions to avoid
None known under normal storage and use conditions.
10.5 Incompatible materials
Reacts with alkali and metals. Keep away from products containing chlorine-based bleaching agents or sulphites.
10.6 Hazardous decomposition products
None known under normal storage and use conditions.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Mixture data:.
Relevant calculated ATE(s):
ATE - Oral (mg/kg): >
Substance data, where relevant and available, are listed below:.
Acute toxicity
Acute oral toxicity Ingredient(s) Endpoint Value (mg/kg) Species Method Exposure time (h) phosphoric acid LD 50 2600 Rat OECD 423 (EU B.1 tris) alkyl alcohol ethoxylate LD 50 > 300 - 2000 Rat OECD 423 (EU B.1 tris) Acute dermal toxicity Ingredient(s) Endpoint Value (mg/kg) Species Method Exposure time (h) phosphoric acid LD 50 2740 Rabbit Method not given alkyl alcohol ethoxylate LD 50 > 2000 Rabbit Method not given Acute inhalative toxicity Ingredient(s) Endpoint Value (mg/l) Species Method Exposure time (h) phosphoric acid LC 50 850 Rat Method not given 2 alkyl alcohol ethoxylate No data available
Method / remark
Autoignition temperature: Not determined
Viscosity: Not determined
Explosive properties: Not explosive.
Oxidising properties: Not oxidising.
Surface tension (N/m): Not determined Not relevant to classification of this product
Corrosion to metals: Corrosive Weight of evidence
Lifeguard Limescale Remover
available alkyl alcohol ethoxylate No data available Chronic toxicity Ingredient(s) Exposure route Endpoint Value (mg/kg bw/d) Species Method Exposure time Specific effects and organs affected Remark phosphoric acid No data available alkyl alcohol ethoxylate Oral NOAEL 50 Rat Method not given 24 month(s) Effects on organ weights STOT-single exposure Ingredient(s) Affected organ(s) phosphoric acid No data available alkyl alcohol ethoxylate Not applicable STOT-repeated exposure Ingredient(s) Affected organ(s) phosphoric acid No data available alkyl alcohol ethoxylate Not applicable
Aspiration hazard
Substances with an aspiration hazard (H304), if any, are listed in section 3. If relevant, see section 9 for dynamic viscosity and relative density
of the product.
Potential adverse health effects and symptoms
Effects and symptoms related to the product, if any, are listed in subsection 4.2.
SECTION 12: Ecological information
12.1 Toxicity
No data is available on the mixture.
Substance data, where relevant and available, are listed below:
Aquatic short-term toxicity
Aquatic short-term toxicity - fish Ingredient(s) Endpoint Value (mg/l) Species Method Exposure time (h) phosphoric acid LC 50 138 Gambusia affinis Method not given 96 alkyl alcohol ethoxylate LC 50 1 - 10 Cyprinus carpio OECD 203 (EU C.1) 96 Aquatic short-term toxicity - crustacea Ingredient(s) Endpoint Value (mg/l) Species Method Exposure time (h) phosphoric acid EC 50 > 100 Daphnia magna Straus
OECD 202 (EU C.2) 48
alkyl alcohol ethoxylate EC 50 1 - 10 Daphnia magna Straus OECD 202, static 48 Aquatic short-term toxicity - algae Ingredient(s) Endpoint Value (mg/l) Species Method Exposure time (h) phosphoric acid EC 50 > 100 Desmodesmus subspicatus
OECD 201 (EU C.3) 72
alkyl alcohol ethoxylate EC 50 1 - 10 Desmodesmus subspicatus OECD 201, static 72 Aquatic short-term toxicity - marine species Ingredient(s) Endpoint Value (mg/l) Species Method Exposure time (days) phosphoric acid No data available
alkyl alcohol ethoxylate No data available
Impact on sewage plants - toxicity to bacteria Ingredient(s) Endpoint Value (mg/l) Inoculum Method Exposure time phosphoric acid EC 50 270 Activated sludge Method not given alkyl alcohol ethoxylate EC 10 > 10000 Activated sludge DIN 38412 / Part 8 17 hour(s)
Lifeguard Limescale Remover
Aquatic long-term toxicity
Aquatic long-term toxicity - fish Ingredient(s) Endpoint Value (mg/l) Species Method Exposure time Effects observed phosphoric acid No data available alkyl alcohol ethoxylate No data available Aquatic long-term toxicity - crustacea Ingredient(s) Endpoint Value (mg/l) Species Method Exposure time Effects observed phosphoric acid No data available alkyl alcohol ethoxylate No data available Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available: Ingredient(s) Endpoint Value (mg/kg dw sediment) Species Method Exposure time (days) Effects observed phosphoric acid No data available
alkyl alcohol ethoxylate No data available
Terrestrial toxicity
Terrestrial toxicity - soil invertebrates, including earthworms, if available: Ingredient(s) Endpoint Value (mg/kg dw soil) Species Method Exposure time (days) Effects observed phosphoric acid No data available
alkyl alcohol ethoxylate NOEC 220 Eisenia fetida - Terrestrial toxicity - plants, if available: Ingredient(s) Endpoint Value (mg/kg dw soil) Species Method Exposure time (days) Effects observed phosphoric acid No data available
alkyl alcohol ethoxylate NOEC 10 Lepidium sativum
OECD 208 -
Terrestrial toxicity - birds, if available: Ingredient(s) Endpoint Value Species Method Exposure time (days) Effects observed phosphoric acid No data available
alkyl alcohol ethoxylate No data available
Terrestrial toxicity - beneficial insects, if available: Ingredient(s) Endpoint Value (mg/kg dw soil) Species Method Exposure time (days) Effects observed phosphoric acid No data available
alkyl alcohol ethoxylate No data available
Terrestrial toxicity - soil bacteria, if available: Ingredient(s) Endpoint Value (mg/kg dw soil) Species Method Exposure time (days) Effects observed phosphoric acid No data available
alkyl alcohol ethoxylate No data available
12.2 Persistence and degradability
Abiotic degradation
Abiotic degradation - photodegradation in air, if available: Abiotic degradation - hydrolysis, if available: Abiotic degradation - other processes, if available:
Biodegradation
Ready biodegradability - aerobic conditions
Lifeguard Limescale Remover
Classification code: C
Tunnel restriction code: E
Hazard identification number: 80
IMO/IMDG
EmS: F-A, S-B
The product has been classified, labelled and packaged in accordance with the requirements of ADR and the provisions of the IMDG Code
Transport regulations include special provisions for certain classes of dangerous goods packed in limited quantities.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations:
- Regulation(EC)No1 272 / 200 8-CLP
- Regulation(EC)No. 1907 / 200 6-REACH
- Regulation(EC)No. 648 / 200 4-Detergentsregulation
Authorisations or restrictions (Regulation (EC) No 1907/2006, Title VII respectively Title VIII): Not applicable.
Ingredients according to EC Detergents Regulation 648/
non-ionic surfactants < 5%
perfumes, Hexyl Cinnamal, Butylphenyl Methylpropional
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.
648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be
made available to them, at their direct request or at the request of a detergent manufacturer.
15.2 Chemical safety assessment
A chemical safety assessment has not been carried out on the mixture
SECTION 16: Other information
The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product
features and does not establish a legally binding contract
Reason for revision:
This data sheet contains changes from the previous version in section(s):, 2, 3, 16
Classification procedure
The classification of the mixture is in general based on calculation methods using substance data, as required by Regulation (EC) No
1272/2008. If for certain classifications data on the mixture is available or for example bridging principles or weight of evidence can be used for
classification, this will be indicated in the relevant sections of the Safety Data Sheet. See section 9 for physical chemical properties, section 11
for toxicological information and section 12 for ecological information.
Full text of the H and EUH phrases mentioned in section 3:
- H 29 0-Maybecorrosivetometals.
- H 30 2-Harmfulifswallowed.
- H 31 4-Causessevereskinburnsandeyedamage.
- H 31 8-Causesseriouseyedamage.
Abbreviations and acronyms:
- AISE-TheinternationalAssociationforSoaps,DetergentsandMaintenanceProducts
- DNEL-DerivedNoEffectLimit
- EUH -CLPSpecifichazardstatement
- PBT-Persistent,BioaccumulativeandToxic
- PNEC -PredictedNoEffectConcentration
- REACH number-REACH registrationnumber,withoutsupplierspecificpart
- vPvB-veryPersistentandveryBioaccumulative
- ATE-AcuteToxicityEstimate
End of Safety Data Sheet
SDS code: MSDS4553 Version: 07.
Revision: 2017-09-
