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Polarity of bonds and molecules, Study notes of Organic Chemistry

description and definition of polarity of bonds and molecules

Typology: Study notes

2022/2023

Available from 06/12/2023

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POLARITY OF BONDS AND MOLECULES
Polarity: definition
In chemical bonding, polarity refers to the distribution of electrical
charge across the atoms joined by the bond. Hydrogen chloride, for
example, has a slightly positively charged hydrogen atom and a slightly
negatively charged chlorine atom.
Polarity of bonds:
Bond Polarity is the measure of the extent to which a bond exhibits
polarity. In simple words, a bond polarity is a scientific tool that gives us
an idea about the nature of the bonds and the type of bonding they will
undergo to form compounds negative end.
The polarity of bonds is caused due to the interaction of the bonds
between molecules and atoms with different electronegativities. In an H-F
bond, the fluorine atom is more electronegative than that of the Hydrogen
atom. The electrons eventually spend more time at the Fluorine atom.
Hence, this F atom slightly becomes negative whereas the Hydrogen atom
tends to become slightly positive. The reasons which lead to the polarity of
bonds are:
1. The electronegativity difference between the combining atoms.
2. Formation of a dipole.
Formation of a diapole:
A covalent bond involves the mutual sharing of valence electrons of
the participating atom. This mutual sharing of electrons takes place to attain
the stable electronic configuration of the neighbouring noble gas atom.
When atoms share their electrons, it tends to happen that the atom
having higher electronegativity than the other pulls the shared pair of
electrons more towards itself. This unequal sharing of electron pairs leads
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POLARITY OF BONDS AND MOLECULES

Polarity: definition In chemical bonding, polarity refers to the distribution of electrical charge across the atoms joined by the bond. Hydrogen chloride, for example, has a slightly positively charged hydrogen atom and a slightly negatively charged chlorine atom. Polarity of bonds: Bond Polarity is the measure of the extent to which a bond exhibits polarity. In simple words, a bond polarity is a scientific tool that gives us an idea about the nature of the bonds and the type of bonding they will undergo to form compounds negative end. The polarity of bonds is caused due to the interaction of the bonds between molecules and atoms with different electronegativities. In an H-F bond, the fluorine atom is more electronegative than that of the Hydrogen atom. The electrons eventually spend more time at the Fluorine atom. Hence, this F atom slightly becomes negative whereas the Hydrogen atom tends to become slightly positive. The reasons which lead to the polarity of bonds are:

  1. The electronegativity difference between the combining atoms.
  2. Formation of a dipole. Formation of a diapole: A covalent bond involves the mutual sharing of valence electrons of the participating atom. This mutual sharing of electrons takes place to attain the stable electronic configuration of the neighbouring noble gas atom. When atoms share their electrons, it tends to happen that the atom having higher electronegativity than the other pulls the shared pair of electrons more towards itself. This unequal sharing of electron pairs leads

to the formation of dipoles (22 poles), and the molecules exhibiting this property are called Polar molecules. The formation of a dipole results in a charge separation in such a type of bond, with one atom being slightly more positive and the other being more negative. The charge separation present in a molecule of a polar covalent compound is called the dipole moment. As dipole formation is a characteristic of bond polarity, the molecules exhibiting dipoles are more precisely called Polar covalent molecules. Due to the unequal sharing of bonding pair of electrons, the atom with a higher electronegative value develops a slightly negative charge (−δ)(−δ). Conversely, the atom with a less electronegative value acquires a slightly positive charge (+δ)(+δ). This charge separation in polar covalent bonds due to the electronegativity difference is called a dipole moment. If a molecule has more dipole moments than the other, it is more polar than other molecules. Thus, dipole moment tells us the degree of polarity in a polar covalent bond. in a polar covalent bond, the two bonded atoms do not share the electrons equally, unless the bond connects two atoms of the same element. There will always be one atom that attracts the electrons in the bond more strongly than the other atom. The ability of an atom to attract electrons in the presence of another atom is a measurable property called electronegativity and will produce a dipole moment. Dipole moments are generally found in Polar Covalent Bonds. A covalent bond with an unequal sharing of electrons and the electronegativity difference within the range of 0.1−20.1−2 is called a polar covalent bond. A covalent bond with an equal share of electrons and an electronegativity difference of zero is called a nonpolar covalent bond.

**Factors on which the Polarity of Bonds Depends

  1. Relative Electronegativity of Participating Atoms** Since the bond polarity involves pulling of electrons towards itself, hence a more electronegative element will be able to attract the electrons more towards itself. As a result, the electrons will definitely move towards the more electronegative element. The amount of their shifting will depend upon the relative electronegativity of the participating atoms. 2) The Spatial Arrangement of Various Bonds in the Atom The shared pair of electrons also experience pulling force from the other bonded and non-bonded pair of electrons. This results in different bond polarity between same participating atoms that are present in different molecules. For e.g. Bond Polarity of O-H bond in a water molecule and acetic acid molecule is different. This is due to the different spatial arrangement of various bonds in the molecule. Polarity of molecules:A state or a condition of an atom or a molecule inherent in a body that exhibits opposite properties or powers in opposite parts or directions .” The bond or the molecular polarities are related to the electronegativities of the atoms or the molecules. A molecule can basically be either polar molecule, non-polar molecule or an ionic molecule. Polar Molecules

A polar molecule usually forms when the one end of the molecule is said to possess a number of positive charges and whereas the opposite end of the molecule has negative charges. Thus, they end up creating an electrical pole. In a molecule having a polar bond, the centre of the negative charge will be on one side. Whereas the centre of positive charge will be on the different side. The entire molecule will be a polar molecule. Non- Polar Molecules A molecule which does not have the charges present at the end due to the reason that electrons are finely distributed and those which symmetrically cancel out each other are the non- polar molecules. In a solution, we cannot mix a polar molecule with the non-polar molecule. For example, consider water and oil. In this solution, water is the polar molecule. On the other hand, oil behaves as a non-polar molecule. These two molecules do not form a solution. This is because they cannot ever be mixed up. What are the Factors that Determine Whether a Molecule Is Polar?

  • If the molecule or atom is perfectly symmetric, the molecule will not be polar even if there are polar bonds present.
  • Polar bonds are formed when one atom in the bond has a much tougher pull towards electrons than the other atom. The difference in strength can be expected by comparing electronegativity values. If one electronegativity value is greater, that atom will pull the electron closer and develop a partial negative charge, while the other atom develops a partial positive charge.