Helium-3 Phase Diagram: Fermi Liquid Theory and Superfluidity, Slides of Chemistry

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Helium-3, Phase diagram

High temperatures

the polycritical point

Logarithmic temperature scale

Fermi liquid theory

Start with a noninteracting Fermi gas and turn on interactions slowly, then you get a Fermi liquid.

Developed by Landau in the 50ies

Describes quasiparticles which can be thought of as dressed helium atoms with an effective mass m*

A mean time between collotions

c^ is defined.

Zero sound for frequencies

c^

similar to plasmon s in a collisionless plasma.

Helium has two properties which is different from ordinary Fermi gases

1. At low temperature the specific heat has the unusual form

C

V

aT

bT

(^) 3

ln

T

the ln term can be explained by so called para magnons. The fluctuations where the neighboring

atoms are aligned will have a long life time.

2. Below 300 mK the liquid has lower entropy than the solid

S

liquid

T

S

solid

R

ln

constant

c.f. Pomeranchuck cooling

Different phases, Predictions

Theory came before experiments, spin triplet p-wave pairing

Cooper pairing, p state (L=1) with less “weight” at r=0.

The ABM phase

Anderson and Morel (1961)

S=

AM

(^) , or

AM

First suggested

Anisotropic

No gap along x-axis

Energy lowered by paramagnetic

interactions via so called paramagnons

Anderson and Brinkman (1973)

The BW phase

Balian and Werthamer (1963)

S=

BW

Lower energy

Isotropic

Same gap for different directions

PW Anderson

The observation of Superfluidity

Lee, Osheroff and Richardson studied Helium three in a Pomeranchuck cell (1972). Nobel Prize (1996)

They observed very small kinks and steps during cooling, similar kins

and steps occurred at the same temperature also on warming

Nuclear Magnetic resonance measurements of the A phase. Note the

shifted peak as a function of pressure.

The A1 phase

A new phase was discovered at finite magnetic field.

A mgnetic superfluid exist in a very narrow rang of magnetic field. Symmetry is broken

since

is favored over

Specific heat shows two transitions in an

applied magnetic field

Ambegaokar and Mermin (1973)

A three dimensional phase diagram

Always two phases at any magnetic field

The explanation of Anthony Leggett (Nobelprize 2003)

Different kinds of symmetry breaking

o

(^) Breaking of guage invariance gives a well defined phase as in superconductors

o

(^) Breaking of rotational symmetry of spin gives a spontaneous field as in magnets

o

(^) Breaking of orbital rotation symmetry gives a preferred direction as in liquid crystals.

The wave function can be described by 3 orbital substates, Lmomentum.Each atom (quasiparticle) can be seen as carrying two vectors, one for spin and one for orbital

Z =0,±1, and three spin substates

S

Z =0,±1. All in all there are 3x3=9 substates, i.e. you need 18 parameters (real and imaginary

part) to describe the system.

Studying vortices in Helium-

Rotating a cryostat that reaches 1 mK (Helsinki)

Persistant angular momentum

Nothing happens until the angular frequency

reaches

c
1 rad/s.

No degradation of the persistant current over 48

hours, from this it can be concluded that the viscosity is at least 12 orders of magnitude higher in the superfluid phase than in the

normal phase.

Note there is no persistant angular momentum in the A phase since it has a node in the gap,

and thus excitations can be created.