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Exploring Alternative Fuels: Reducing Reliance on Petroleum, Assignments of Thermodynamics

An in-depth analysis of various alternative fuels that can help reduce our reliance on petroleum-based fuels. It covers the characteristics, production methods, and environmental impact of fuels such as methanol, ethanol, natural gas, liquefied petroleum gas, hydrogen, and biodiesel. The document highlights the advantages and disadvantages of each fuel, as well as the potential for their widespread adoption. It also discusses the role of electricity, including battery-powered and fuel cell-powered vehicles, in the transition towards more sustainable transportation. The document emphasizes the importance of developing alternative fuels to address the economic and environmental challenges posed by our current dependence on finite and polluting petroleum resources. By exploring these alternative options, the document aims to guide readers towards a more sustainable energy future.

Typology: Assignments

2020/2021

Uploaded on 07/28/2022

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The increasing motorization
increasing motorization of the world
has led to a steep rise in the demand of
petroleum products. But petroleum
resources are :
Finite
Highly concentrated in certain
regions of the world
Source of environmental
pollution.
Background
Background
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The

increasing motorization

increasing motorization

of the world

has led to a steep rise in the demand ofpetroleum

products.

But

petroleum

resources are :



Finite



Highly concentrated in certainregions of the world



Source of environmentalpollution.

Background

Background

The

transportation

sector

consumes

percent

of

the

total

petroleum

products

supplied. In India, the transportation sectorcontributes:

about 1/3rd of CO

2

emissions

about 1/3rd of NOx emissions

nearly 77 % of CO emissions

around 45 % of particulate matter (PM)

Background

Background

Alternative fuels include :

Alternative fuels include :

Methanol and ethanol (Alcohol fuels)

Methanol and ethanol (Alcohol fuels)

Natural gas (compressed or liquefied)

Natural gas (compressed or liquefied)

Liquefied petroleum gas

Liquefied petroleum gas

Hydrogen

Hydrogen

Biodiesel

Biodiesel

Electricity (Batteries and Fuel Cells)

Electricity (Batteries and Fuel Cells)

Methanol

Methanol

What it is

What it is

Methanol is an alcohol fuel. The

primary

alternative

methanol

fuel

being

used

is

M-85,

which

is

made

up

of

percent

methanol

and

percent

gasoline.

In the future, neat methanol (M-100), mayalso be used.

How it is produced: How it is produced:

Methanol is created from

a synthesis gas (hydrogen and CO), which isreacted in the presence of a catalyst.Methanol can also be produced from non-petroleum feed-stocks such as coal andbiomass.

What it is What it is

: :

It’s a cheap non-petroleum based fuel. As with

methanol, E-85 is the primary ethanol alternative fuel. Theuse of ethanol in vehicles is not a new innovation. In the1880s, Henry Ford built one of his first automobiles to run onethanol.

There's enough alcohol in one year's yield of an acre of potatoeThere's enough alcohol in one year's yield of an acre of potatoeThere's enough alcohol in one year's yield of an acre of potatoeThere's enough alcohol in one year's yield of an acre of potatoes to drive the

s to drive thes to drive thes to drive the

machinery necessary to cultivate the fields for one hundred yearmachinery necessary to cultivate the fields for one hundred yearmachinery necessary to cultivate the fields for one hundred yearmachinery necessary to cultivate the fields for one hundred years.

s.s.s.

-

Henry Ford

How is it produced How is it produced

: :

It can be produced by fermentation of

vegetables and plant materials. In India, its main source ismolasses - a byproduct of sugarcane. Its done in threestages1. Extraction of juice from sugarcane2. Fermentation of the juice3. Distillation

Ethanol

Ethanol

Environmental Characteristics Environmental Characteristics

It has approximately

fewer

smog

forming

emissions

than

a

gasoline

vehicle.

Air

toxics

are

also

reduced

by

about 50 percent when compared to gasoline. Aswith all internal combustion engines, vehicles usingethanol emit minor amounts of aldehydes. This isresolved

by

installing

advanced

catalytic

converters on the vehicles. Major problem

with ethanol is the corrosion. Ethanol

driven vehicles require lines, hoses and valves

to

be

resistant

to

the

corrosion

that

alcohol

can

induce.

Alcohol

corrodes

lead-plated

fuel

tanks;

magnesium,

copper,

lead,

zinc,

and

aluminum

parts; and some synthetic gaskets.

Advantages

Advantages 1. Its cheap2. It’s Engine-Friendly3. It’s safe4. There is lot of it in India.5. It’s clean, easy to trap and odorless.

Disadvantages

Disadvantages 1. The storage cylinder takes a lot of space.2. CNG gas stations are not widely available in India.

Liquified

Liquified

Petroleum Gas

Petroleum Gas

LPG

LPG

What it is

What it is

Liquefied petroleum gas (LPG) consists

of

various

hydrocarbons,

mainly

propane,

propylene,

butane,

and

butylene

in

various

mixtures. The main constituent, in most of thecases , is propane.

How it is produced

How it is produced

LPG is a byproduct of natural

gas processing and petroleum refining.

Environmental

Characteristics

Environmental

Characteristics

The

LPG

run

vehicles

have

lower

emission

of

reactive

hydrocarbons

(about

one-third

less),

NOx

percent

less),

and

CO

percent

less)

than

gasoline vehicles.

Hydrogen (H

Hydrogen (H

2 2

What it is What it is

Hydrogen gas (H

2

How it is produced How it is produced

Hydrogen can be produced from

a number of different sources, including natural gas,water, methanol etc. Two methods are generally usedto produce hydrogen:

(1) Electrolysis(2) Synthesis gas production from steam reforming

or partial oxidation.

Environmental

Characteristics

Environmental

Characteristics

When

combusted

(oxidized),

only

water

vapor

is

produced.

When

burned

in

an

internal

combustion

engine,

small

amounts

of

nitrogen

oxides

and

small

amounts

of

unburned hydrocarbons and carbon monoxide areproduced, due to the use of engine lubricants.

Advantages Advantages

Hydrogen-air

mixture

burns

nearly

times

faster than gasoline-air mixture.

Hydrogen has high self-ignition temperature butrequires very little energy to ignite it.

Clean exhaust, produces no CO

2

As a fuel it is very efficient as there are no lossesassociated with throttling.

Disadvantages Disadvantages



There

is

danger

of

back

fire

and

induction

ignition.

Though low in exhaust , it produces toxic NOx.

Its difficult to handle and store, requiring high

capital and running cost.

Environmental

Characteristics

Environmental

Characteristics

Biodiesel

has no aromatic content and only traceamounts of sulfur. In vehicle tests, it haslower

emissions

of

carbon

monoxide,

soot,

and

polycyclic

aromatic

hydrocarbons than conventional diesel.With adjustments in the injection enginetiming, it is possible to reduce the NOxemissions.

Biodiesel

Biodiesel

Advantages Advantages



Low Emissions



It is biodegradable and non-toxic



Low cost



High Cetane Number



High Lubricidity

Batteries are the storage "tanks" forelectricity,

and

the

quantity

of

potential power available from themis

given

by

the

battery

rating

(determined by plate size, quantity ofelectrolyte, etc.).

Batteries

Batteries

Fuel cells do not store energy; insteadchemical

energy

is

converted

into

electricity.

An

external

source

of

hydrogen (for example, from naturalgas, gasoline, or one of the alcoholfuels) and oxygen (from air) are fed tothe fuel cell. The electrolyte fuel cellsemploy the electrochemical reactionbetween

hydrogen

and

oxygen

to

generate electricity.

Fuel Cells

Fuel Cells